Bis{4-chloro-N′-[phenyl(2-pyridyl)methylidene]benzohydrazidato-κ2N′,O}cobalt(III) nitrate methanol disolvate
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3-Chloro-N′-(4-hydroxy-3-nitrobenzylidene)benzohydrazide methanol disolvate
In the title compound, C(14)H(10)ClN(3)O(4)·2CH(4)O, the main mol-ecule is in an E configuration with respect to the methyl-idene unit. The dihedral angle between the mean planes of the two benzene rings is 1.9 (3)°. In the crystal, inter-molecular N-H⋯O, O-H⋯O and bifurcated O-H⋯(O, O) hydrogen bonds link the components into sheets parallel to (100). An intra-molecular O-H⋯O hydrogen bond is a...
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IN THE CRYSTAL OF THE TITLE COMPOUND [SYSTEMATIC NAME: 2-(3,5-diamino-6-chloro-pyrazin-2-ylcarbon-yl)guanidinium chloride methanol disolvate], C(6)H(9)ClN(7)O(+)·Cl(-)·2CH(3)OH , the components are connected by N-H⋯N, N-H⋯Cl, N-H⋯O, O-H⋯Cl and O-H⋯O hydrogen bonds into a three-dimensional network. The dihedral angle between the aromatic ring and the guanidine residue is 6.0 (2)°.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810032241